The white ball is a type of check valve to prevent flooding the basement in case of a back-up.. It is an addition to the drain pipe. Caustic chemicals rarely work on clogs. They eat a small hole in the clog and then drain away down the rest of the pipe, leaving a partial clog to start the process all over again. Enzyme drain cleaners stick to, and eat organic clogs. 5 hours is not really enough time for an enzyme cleaner. I think you need an auger run through the piping.
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