Personally, I would not spray oil on PEX - that's my gut instinct. I heard allegations that WD-40 was sometimes sprayed on CPVC during installation to make it easier to push through the holes in the joists, and future problems occurred with the pipe. Again, this was an allegation and I never saw any documentation to substantiate this claim.
Your best bet would be to send an email to a PEX pipe manufacturer or check their website for FAQ's that may address this.
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