Sorry, I don't have experience with heat pumps but, now that I think about it, you should have 24volts on both the switching valve and the A/C circuit.
The blue is to run the A/C and the orange would reverse the A/C into heat mode. So yes, it could be the open ambient temp sensor holding out the voltage to the blue A/C wire. As a test, you could bypass the ambient sensor with a piece of wire and see if this allows the A/C to run.
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