Unfortunately, there is no feasible means of telling weather or not it's R22 or otherwise.
The other caveat would be that he is selling recovered freon, in which case it got evac'd into a grey tank w/a yellow top.
If it's not R22 and you use it in an R22 system you'll damage the system.
I wouldn't take the chance unless I recovered it personally, it's just not worth the risk.
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