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You can use a product called 'Whink Rust stain remover' and it works like a dream. To be used on white toilets and tubs only.

I had the same problem wit a stained toilet. My neighbor gave me this product called "Whink". You can buy it at a hardware store or you can get it online - it is a miraculous. To be used on white toilts and tubs only. The stain will disappear immediately. It's a must try.